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Material Identification
Formula : CCl3F
Molecular Weight : 137.36
Tradenames and Synonyms
F-11
CC0119
Company Identification
MANUFACTURER/DISTRIBUTOR
Leempeng Enterprise (Pte) Ltd
No. 7 Kallang Way 5
Kolam Ayer Industrial Park
Singapore (349026) PHONE NUMBERS
Product Information : (65) 97483334
Transport Emergency : (65) 97483334
Medical Emergency : (65) 97483334 Components
Material CAS Number %
*METHANE, TRICHLOROFLUORO- ("PORTA" 11) 75-69-4 100
* Disclosure as a toxic chemical is required under Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR part 372.
Potential Health Effects
Inhalation of high concentrations of vapor is harmful and
may cause heart irregularities, unconsciousness, or death.
Intentional misuse or deliberate inhalation may cause death
without warning. Vapor reduces oxygen available for
breathing and is heavier than air. Causes skin and eye
irritation.
HUMAN HEALTH EFFECTS:
Human health effects of overexposure by eye contact may
include eye irritation with discomfort, tearing, or blurring
of vision. Skin contact with the liquid may cause drying of
the skin with repeated contact resulting in mild skin
irritation with discomfort or rash. Overexposure by
inhalation may cause temporary nervous system depression
with anesthetic effects such as dizziness, headache,
confusion, incoordination, and loss of consciousness;
temporary alteration of the heart's electrical activity with
irregular pulse, palpitations, or inadequate circulation, or
the effects of exclusion of oxygen with grossly excessive
exposures. Ingestion may include nonspecific discomfort,
such as nausea, headache, or weakness.
Individuals with preexisting diseases of the central nervous
or cardiovascular system may have increased susceptibility
to the toxicity of excessive exposures.
Carcinogenicity Information
None of the components present in this material at concentrations
equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH
as a carcinogen.
First Aid
INHALATION
If high concentrations are inhaled, immediately remove to
fresh air. Keep person calm. If not breathing, give
artificial respiration. If breathing is difficult, give
oxygen. Call a physician.
SKIN CONTACT
In case of skin contact, flush skin with plenty of water
for 15 minutes. Get medical attention if irritation is
present.
EYE CONTACT
In case of eye contact, immediately flush eyes with
plenty of water for 15 minutes. Call a physician.
INGESTION
If swallowed, no specific intervention is indicated as
the compound is not likely to be hazardous by ingestion.
However, consult a physician if necessary.
Notes to Physicians
Because of possible disturbances of cardiac rhythm,
catecholamine drugs, such as epinephrine, should be used
with special caution in situations of emergency life
support.
Flammable Properties
Flash Point : Will not burn
Method : TOC
Flammable limits in Air, % by Volume
LEL : Not applicable
UEL : Not applicable
Autoignition : Not determined
Autodecomposition : >593 C (>1099 F)
Fire and Explosion Hazards:
Drums may rupture under fire conditions. Decomposition may
occur.
Extinguishing Media
As appropriate for combustibles in area.
Fire Fighting Instructions
Self-contained breathing apparatus (SCBA) is required if
containers rupture and contents are spilled under fire
conditions. Water runoff should be contained and
neutralized prior to release.
Safeguards (Personnel)
NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL)
sections before proceeding with clean-up. Use appropriate
PERSONAL PROTECTIVE EQUIPMENT during clean-up.
Accidental Release Measures
Ventilate area. Do not flush into sewers. Dike spill.
Collect on absorbent material and transfer to steel drums
for recovery or disposal. Use self-contained breathing
apparatus (SCBA) for large spills. Comply with Federal,
State and local regulations on reporting releases.
Handling (Personnel)
Use with sufficient ventilation to keep employee exposure
below recommended limits.
Storage
Clean, dry area. Do not store above 125 deg F (52 deg C).
Engineering Controls
Normal ventilation for standard manufacturing procedures
is generally adequate. Local exhaust should be used when
large amounts are released. Mechanical ventilation
should be used in low or enclosed places.
Personal Protective Equipment
Impervious gloves should be used to avoid prolonged or
repeated exposure. Chemical splash goggles should be
available for use as needed to prevent eye contact. Under
normal manufacturing conditions, no respiratory protection
is required when using this product. Self-contained
breathing apparatus (SCBA) is required if a spill occurs.
# Exposure Guidelines
Exposure Limits
"PORTA" 11
PEL (OSHA) : 1,000 ppm, 5,600 mg/m3, 8 Hr. TWA
TLV (ACGIH) : Ceiling 1,000 ppm, 5,620 mg/m3, A4
AEL * : None Established
* AEL is Acceptable Exposure Limit. Where governmentally
imposed occupational exposure limits which are lower than the AEL
are in effect, such limits shall take precedence.
Physical Data
Boiling Point : 23.9 C (75 F)
Vapor Pressure : 14.7 psia at 25 deg C (77 deg F)
Vapor Density : 4.9 (Air = 1)
% Volatiles : 100 WT%
Evaporation Rate : (CCl4 = 1)
Greater than 1
Solubility in Water : 0.1 WT% @ 25 C (77 F)
pH : Neutral
Odor : Slight ethereal
Form : Liquid
Color : Colorless
Density : 1.48 g/cc at 25 deg C (77 deg F)
Appearance : Clear
Chemical Stability
Stable.
However, avoid open flames and high temperatures.
Incompatibility with Other Materials
Incompatible with alkali or alkaline earth metals- powdered
Al, Zn, Be, etc.
Decomposition
Decomposition products are hazardous. PORTA 11 can be
decomposed by high temperatures (open flames, glowing metal
surfaces, etc.) forming hydrochloric and hydrofluoric acids,
and possibly carbonyl halides. These materials are toxic
and irritating. Contact should be avoided.
Polymerization
Polymerization will not occur.
Animal Data
Inhalation 4-hour LC50: 26,200 ppm in rats
Oral ALD : 3725 mg/kg in rats
The compound is not a skin irritant but is a mild eye
irritant. Toxic effects in rats exposed by inhalation
include central nervous system and anesthetic effects at
high concentrations. Concentrations of 0.35% and higher
caused cardiac sensitization in dogs. Various
cardiovascular and circulatory abnormalities have also been
reported in other animals. Changes in the lungs, liver,
brain and spleen were observed in a study of rats exposed by
inhalation to 12 times the TLV. In another study at 25
times the TLV, rats, guinea pigs, and cats exhibited no
microscopic evidence of damage to the heart, lungs, kidney,
liver or spleen. Exposures by ingestion or skin resulted in
no evidence of toxicity in rats, dogs or rabbits.
Ecotoxicological Information
Aquatic Toxicity
"PORTA" 11: 96-hour LC50, rainbow trout: 190 mg/L
Waste Disposal
Reclaim by distillation or remove to a permitted waste
disposal facility. Comply with Federal, State, and local
regulations.
Shipping Information
DOT
DOT/IMO
Proper Shipping Name : RQ ENVIRONMENTALLY HAZARDOUS SUBSTANCE
LIQUID, N.O.S.
(TRICHLOROFLUOROMETHANE)
Hazard Class : 9
UN No. : 3082
DOT/IMO Label : CLASS 9
Packing Group : III
Shipping Containers
Tank Cars.
Tank Trucks.
Drums.
Reportable Quantity : 5000 lb
NOT REGULATED AS A HAZARDOUS MATERIAL BY DOT, IMO OR ICAO IN
CONTAINERS LESS THAN 5000 LBS.
U.S. Federal Regulations
TSCA Inventory Status : Reported/Included.
TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312
Acute : Yes
Chronic : No
Fire : No
Reactivity : No
Pressure : No
HAZARDOUS CHEMICAL LISTS
SARA Extremely
Hazardous Substance - No
CERCLA Hazardous Substance - Yes
SARA Toxic Chemical - See Components Section
Superfund reportable discharge = 5000 lb.
NFPA, NPCA-HMIS
NPCA-HMIS Rating
Health : 1
Flammability : 0
Reactivity : 1
Personal Protection rating to be supplied by user depending on use
conditions.
Additional Information
"PORTA" 11 contains very low levels of carbon tetrachloride
and chloroform, chemicals known to the State of California
to cause cancer.
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The data in this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.
End of MSDS